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Buffett now owns 57,975,456 shares, or a 10% stake in the Texas-based energy company, according to a securities filing posted shortly after 8pm ET.
As of Friday's share price close of $77.23, Buffett's stake is valued at $4.47 billion.
Buffett had been aggressively buying shares of Phillips 66 since Wednesday of this week.
Earlier this month, Buffett had indicated in his 13-F filing that he was building a new position.
Here's a rundown of Buffett's purchases over the last few days.