The footage shows the car passing through the Dapchari check post in Palghar district at 2.21 pm on Sunday, he said.
The car hit a road divider on a bridge over the Surya river on the Mumbai-Ahmedabad Highway at around 3 pm, killing
The police team probing the crash are examining the CCTV footage for further leads, the official said.
Another police officer said the person behind the wheel had covered a distance of 20km in just nine minutes, meaning the luxury car was being driven at a speed of 180-190 km per hour.
The car was being driven by Mumbai-based gynaecologist Anahita Pandole (55), a family friend of Mistry, police have said.
She and her husband Darius Pandole (60) were seriously injured in the accident and are undergoing treatment in a Mumbai hospital.
The probe team will submit a detailed report which will be forwarded to Maharashtra Deputy Chief Minister Devendra Fadnavis, who has ordered an investigation into the road accident, he said.
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